IBS CMSD Seminar_Dr. Minjee Seo (IBS CMSD)(Sep. 09, 2020)
IBS Center for Molecular Spectroscopy and Dynamics
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SPEAKER
Dr. Minjee Seo (IBS
CMSD)
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TITLE
Morphological Effects of Nanoporous Indium Tin Oxide electrodes
towards Electron transfer and its applications as Bipolar electrode sensors
■ ABSTRACT
With the advent of environmental issues and
increasing demands for medical monitoring devices, highly efficient, as well as
cost-effective and stable electrocatalysts are essential nowadays. In
particular, nanoporous electrodes have been applied in diverse energy
conversion devices and sensors owing to its enhanced electrocatalytic activity.
The remarkable electrocatalytic activity effects of the nanoporous electrodes
are usually understood on the basis of its enlarged surface area, crystalline
facets, or surface defects. In the geometrical point of view, nanocavities of
nanoporous electrodes offer unique spatial environment, resulting in altered
physicochemical characteristics. For instance, it has been suggested that
confinement of reactant molecules lead to enhanced interaction between the
reactant molecule and the electrode surface, a phenomenon denoted as
nanoconfinement effects. To clearly observe this ‘nanoconfinement effect’,
nanoporous Indium tin oxide (ITO) electrodes are utilized to investigate the
kinetics of a single electron transfer Fe2+/3+. By varying the nanoporous ITO
layer thickness and comparing their performance, we were able to effectively
exclude electrocatalytic effects originating from the electrode surface, such
as defects. The catalytic effects of nanoporous ITOs were also demonstrated by
its applications in bipolar based sensors.
■ DATE AND VENUE
September 9, 2020 (Wednesday, 5:00 - 6:00)
Seminar Room B (119), KU R&D Center
■ LANGUAGE
Korean